2012년 4월 14일 토요일

MO theory

http://scramlinged.com/resources/Notes+on+Molecular+Orbital+Theory.pdf


Nitrogen molecules are triple bonded as we can see in the following diagram.
nitrogen.gif (5549 bytes)
In this diagram, we can easily see that the MO electronic configuration is (σ2s)2*2s)22p)42p)2 for an overall bond order of 3 (4 bonds - 1 antibond).
We see that there is a (σ2p) bond and two (π2p) bonds holding the molecule together in this model.  The (σ2s) and (σ*2s) cancel each other out and don't contribute to the bonding.

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