2012년 12월 30일 일요일

ionization energy of CO

The ionization energy of CO is greater than that of NO. Explain this difference based on the elctron configuration of these two molecules

Answers (1)

Anonymous
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The HOMO of NO is an anti-bonding molecular orbital, whereas the HOMO of CO is a bonding molecular orbital. The unpaired electron in the antibonding HOMO of NO is higher in energy than those in the bonding HOMO of CO.  Therefore the NO molecule is easier to ionize than CO.

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