2012년 11월 22일 목요일
2012년 11월 18일 일요일
2012년 11월 12일 월요일
뇌하수체종양
http://www.khmc.or.kr/~youngkmc/thalamus/ch55_1.htm
갑상선
기능항진증을 일으키는 TSH 분비 뇌하수체종은 TSH를 생산하는 뇌하수체세포의
종양성 변형에 의해 발생하며, TSH 생산 증가로 갑상선이 과도하게 자극되어
갑상선종과 갑상선 기능항진증이 초래된다. 이 환자의 약
40%에서는 다른 뇌하수체 호르몬의 과다분비가 동반되는데, 주로
성장호르몬과 프로락틴이 과다분비된다.
AlCl3 a lewis acid
The main reason that AlCl3 can occupy a 4th chloride ligand is because
the resulting species: R-Cl-AlCl3 (with a + formal charge on the Cl atom
of the alkyl chloride, and a - formal charge on the Al atom) is
tetrahedral about the Al atom. Tetrahedral aluminum complexes (such as
AlCl4-) are very well known chemical species, however, trigonal planar
aluminum species with a bond order of 4 (such as the case with AlCl3
with a lone-pair of electrons on one of the Cl atoms back-bonded into
the empty p-orbital of the Al atom) are not known. The same is also
observed for boron. Tetrahedral anionic aluminate or borate species are
known, while trigonal planar species with bond order 4 are not.
2012년 11월 8일 목요일
2012년 11월 4일 일요일
Reactions of Monosaccharides
The chemistry of monosaccharides is the chemistry of the component
aldehydes, ketones, and alcohols that make up these molecules. One
example of how the chemistry of carbohydrates is the same as the
chemistry of ketones is in their reaction with NaBH4.
Reduction to Alditols. Both ketoses and aldoses can be reduced with NaBH4 to reduced forms, known as alditols. With ketoses, this often produces 2 diastereomeric alditols.
Reduction to Alditols. Both ketoses and aldoses can be reduced with NaBH4 to reduced forms, known as alditols. With ketoses, this often produces 2 diastereomeric alditols.
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